Demineralizers
Purpose of Demineralizers
Dissolved impurities in power plant fluid systems generate corrosion problems and decrease efficiency due to fouled heat transfer surfaces. Demineralization of the water is one of the most practical and common methods available to remove these dissolved impurities.
In the plant, demineralizers (also called ion-exchangers) are used to hold ion exchange resins and transport water through them. Ion exchangers are generally classified into two groups: single-bed ion exchangers and mixed-bed ion exchangers.
Demineralizers
A demineralizer is basically a cylindrical tank with connections at the top for water inlet and resin addition, and connections at the bottom for the water outlet. The resin can usually be changed through a connection at the bottom of the tank. The resin beads are kept in the demineralizer by upper and lower retention elements, which are strainers with a mesh size smaller then the resin beads. The water to be purified enters the top at a set flow rate and flows down through the resin beads, where the flow path causes a physical filter effect as well as a chemical ion exchange.
Single-Bed Demineralizers
A single-bed demineralizer contains either cation or anion resin beads. In most cases, there are two, single-bed ion exchangers in series; the first is a cation bed and the second is an anion bed. Impurities in plant water are replaced with hydrogen ions in the cation bed and hydroxyl ions in the anion bed. The hydrogen ions and the hydroxyl ions then combine to form pure water. The Chemistry Handbook, Module 4, Principles of Water Treatment, addresses the chemistry of demineralizers in more detail.
Figure 13 illustrates a single-bed demineralizer. When in use, water flows in through the inlet to a distributor at the top of the tank. The water flows down through the resin bed and exits out through the outlet. A support screen at the bottom prevents the resin from being forced out of the demineralizer tank.
Single-Bed Regeneration
The regeneration of a single-bed ion exchanger is a three-step process. The first step is a backwash, in which water is pumped into the bottom of the ion exchanger and up through the resin. This fluffs the resin and washes out any entrained particles. The backwash water goes out through the normal inlet distributor piping at the top of the tank, but the valves are set to direct the stream to a drain so that the backwashed particles can be pumped to a container for waste disposal.
The second step is the actual regeneration step, which uses an acid solution for cation units and caustic solution for anion units. The concentrated acid or caustic is diluted to approximately 10% with water by opening the dilution water valve, and is then introduced through a distribution system immediately above the resin bed. The regenerating solution flows through the resin and out the bottom of the tank to the waste drain.
The final step is a rinsing process, which removes any excess regenerating solution. Water is pumped into the top of the tank, flows down through the resin bed and out at the bottom drain.
To return the ion exchanger to service, the drain valve is closed, the outlet valve is opened, and the ion exchanger is ready for service.
Single-bed demineralizers are usually regenerated “in place.” The resins are not pumped out to another location for regeneration. The regeneration process is the same for cation beds and for anion beds; only the regenerating solution is different. It is important to realize that if the ion exchanger has been exposed to radioactive materials, the backwash, regeneration, and rinse solutions may be highly radioactive and must be treated as a radioactive waste.
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