Science and Engineering Article

Mixed-Bed Demineralizer

A mixed-bed demineralizer is a demineralizer in which the cation and anion resin beads are mixed together. In effect, it is equivalent to a number of two-step demineralizers in series. In a mixed-bed demineralizer, more impurities are replaced by hydrogen and hydroxyl ions, and the water that is produced is extremely pure. The conductivity of this water can often be less than 0.06 micromhos per centimeter.

Mixed-Bed Regeneration

The mixed-bed demineralizer shown in Figure 14 is designed to be regenerated in place, but the process is more complicated than the regeneration of a single-bed ion exchanger. The steps in the regeneration are shown in Figure 14.

Figure 14. Refrigeration of a Mixed-Bed Demineralizer

Figure 14a shows the mixed-bed ion exchanger in the operating, or on-line mode. Water enters through a distribution header at the top and exits through the line at the bottom of the vessel. Regeneration causes the effluent water to increase in electrical conductivity. The first regeneration step is backwash, as shown in Figure 14b. As in a single-bed unit, backwash water enters the vessel at the bottom and exits through the top to a drain. In addition to washing out entrained particles, the backwash water in a mixed-bed unit must also separate the resins into cation and anion beds. The anion resin has a lower specific gravity than the cation resin; therefore, as the water flows through the bed, the lighter anion resin beads float upward to the top. Thus, the mixed-bed becomes a split bed. The separation line between the anion bed at the top and the cation bed at the bottom is called the resin interface. Some resins can be separated only when they are in the depleted state; other resins separate in either the depleted form or the regenerated form.

The actual regeneration step is shown in Figure 14c. Dilution water is mixed with caustic solution and introduced at the top of the vessel, just above the anion bed. At the same time, dilution water is mixed with acid and introduced at the bottom of the vessel, below the cation bed. The flow rate of the caustic solution down to the resin interface is the same as the flow rate of the acid solution up to the resin interface. Both solutions are removed at the interface and dumped to a drain.

During the regeneration step, it is important to maintain the cation and anion resins at their proper volume. If this is not done, the resin interface will not occur at the proper place in the vessel, and some resin will be exposed to the wrong regenerating solution. It is also important to realize that if the ion exchanger has been involved with radioactive materials, both the backwash and the regenerating solutions may be highly radioactive and must be treated as liquid radioactive waste.

The next step is the slow rinse step, shown in Figure 14d, in which the flow of dilution water is continued, but the caustic and acid supplies are cut off. During this two-direction rinse, the last of the regenerating solutions are flushed out of the two beds and into the interface drain. Rinsing from two directions at equal flow rates keeps the caustic solution from flowing down into the cation resin and depleting it. In the vent and partial drain step, illustrated in Figure 14e, the drain valve is opened, and some of the water is drained out of the vessel so that there will be space for the air that is needed to re-mix the resins. In the air mix step, (Figure 14f) air is usually supplied by a blower, which forces air in through the line entering the bottom of the ion exchanger. The air mixes the resin beads and then leaves through the vent in the top of the vessel. When the resin is mixed, it is dropped into position by slowly draining the water out of the interface drain while the air mix continues.

In the final rinse step, shown in Figure 14g, the air is turned off and the vessel is refilled with water that is pumped in through the top. The resin is rinsed by running water through the vessel from top to bottom and out the drain, until a low conductivity reading indicates that the ion exchanger is ready to return to service.

External Regeneration

Some mixed-bed demineralizers are designed to be regenerated externally, with the resins being removed from the vessel, regenerated, and then replaced. With this type of demineralizer, the first step is to sluice the mixed bed with water (sometimes assisted by air pressure) to a cation tank in a regeneration facility. The resins are backwashed in this tank to remove suspended solids and to separate the resins. The anion resins are then sluiced to an anion tank. The two batches of separated resins are regenerated by the same techniques used for single-bed ion exchangers. They are then sluiced into a holding tank where air is used to remix them. The fixed, regenerated, resins are then sluiced back to the demineralizer.

External regeneration is typically used for groups of condensate demineralizers. Having one central regeneration facility reduces the complexity and cost of installing several demineralizers. External regeneration also allows keeping a spare bed of resins in a holding tank. Then, when a demineralizer needs to be regenerated, it is out of service only for the time required to sluice out the depleted bed and sluice a fresh bed in from the holding tank. A central regeneration facility may also include an ultrasonic cleaner that can remove the tightly adherent coating of dirt or iron oxide that often forms on resin beads. This ultrasonic cleaning reduces the need for chemical regeneration.

<< Demineralizer || Pressurizer >>

Purpose of Demineralizers

Dissolved impurities in power plant fluid systems generate corrosion problems and decrease efficiency due to fouled heat transfer surfaces. Demineralization of the water is one of the most practical and common methods available to remove these dissolved impurities.

In the plant, demineralizers (also called ion-exchangers) are used to hold ion exchange resins and transport water through them. Ion exchangers are generally classified into two groups: single-bed ion exchangers and mixed-bed ion exchangers.

Demineralizers

A demineralizer is basically a cylindrical tank with connections at the top for water inlet and resin addition, and connections at the bottom for the water outlet. The resin can usually be changed through a connection at the bottom of the tank. The resin beads are kept in the demineralizer by upper and lower retention elements, which are strainers with a mesh size smaller then the resin beads. The water to be purified enters the top at a set flow rate and flows down through the resin beads, where the flow path causes a physical filter effect as well as a chemical ion exchange.

Single-Bed Demineralizers

A single-bed demineralizer contains either cation or anion resin beads. In most cases, there are two, single-bed ion exchangers in series; the first is a cation bed and the second is an anion bed. Impurities in plant water are replaced with hydrogen ions in the cation bed and hydroxyl ions in the anion bed. The hydrogen ions and the hydroxyl ions then combine to form pure water. The Chemistry Handbook, Module 4, Principles of Water Treatment, addresses the chemistry of demineralizers in more detail.

Figure 13 illustrates a single-bed demineralizer. When in use, water flows in through the inlet to a distributor at the top of the tank. The water flows down through the resin bed and exits out through the outlet. A support screen at the bottom prevents the resin from being forced out of the demineralizer tank.

Single-Bed Regeneration

The regeneration of a single-bed ion exchanger is a three-step process. The first step is a backwash, in which water is pumped into the bottom of the ion exchanger and up through the resin. This fluffs the resin and washes out any entrained particles. The backwash water goes out through the normal inlet distributor piping at the top of the tank, but the valves are set to direct the stream to a drain so that the backwashed particles can be pumped to a container for waste disposal.

The second step is the actual regeneration step, which uses an acid solution for cation units and caustic solution for anion units. The concentrated acid or caustic is diluted to approximately 10% with water by opening the dilution water valve, and is then introduced through a distribution system immediately above the resin bed. The regenerating solution flows through the resin and out the bottom of the tank to the waste drain.

The final step is a rinsing process, which removes any excess regenerating solution. Water is pumped into the top of the tank, flows down through the resin bed and out at the bottom drain.

To return the ion exchanger to service, the drain valve is closed, the outlet valve is opened, and the ion exchanger is ready for service.

Single-bed demineralizers are usually regenerated “in place.” The resins are not pumped out to another location for regeneration. The regeneration process is the same for cation beds and for anion beds; only the regenerating solution is different. It is important to realize that if the ion exchanger has been exposed to radioactive materials, the backwash, regeneration, and rinse solutions may be highly radioactive and must be treated as a radioactive waste.

<< Natural Convection Cooling Towers | Mixed-Bed Demineralizer >>

Natural Convection Cooling Towers

Natural convection cooling towers, illustrated in Figure 12, use the principle of convective flow to provide air circulation. As the air inside the tower is heated, it rises through the tower. This process draws more air in, creating a natural air flow to provide cooling of the water. The basin at the bottom of the tower is open to the atmosphere. The cooler, more dense air outside the tower will flow in at the bottom and contribute to the air circulation within the tower. The air circulation will be self perpetuating due to the density difference between the warmer air inside and the cooler air outside.

The incoming water is sprayed around the circumference of the tower and cascades to the bottom. The natural convection cooling towers are much larger than the forced draft cooling towers and cost much more to construct. Because of space considerations and cost, natural convection cooling towers are built less frequently than other types.

<< Induced Draft Cooling Towers | Demineralizers>>

Induced Draft Cooling Towers

Induced draft cooling towers, illustrated in Figure 11, are constructed such that the incoming circulating water is dispersed throughout the cooling tower via a spray header. The spray is directed down over baffles that are designed to maximize the contact between water and air. The air is drawn through the baffled area by large circulating fans and causes the evaporation and the cooling of the water.

The nomenclature for induced draft cooling towers, including some items not illustrated in Figure 11 is summarized below.

• Casing -The casing encloses the walls of the cooling tower, exclusive of fan deck and louvers.
• Collecting basin -The collecting basin is a receptacle beneath the cooling tower for collecting the water cooled by the cooling tower. It can be made of concrete, wood, metal, or an alternative material. Certain necessary accessories are required such as sump, strainers, overflow, drain, and a makeup system.
• Drift eliminators -The drift eliminators are parallel blades of PVC, wood, metal, or an alternative material arranged on the air discharge side of the fill to remove entrained water droplets from the leaving air stream.
• Driver -The driver is a device that supplies power to turn the fan. It is usually an electric motor, but turbines and internal combustion engines are occasionally used.
• Drive shaft -The drive shaft is a device, including couplings, which transmits power from the driver to the speed reducer.
• Fan -The fan is a device used to induce air flow through the cooling tower.
• Fan deck -The fan deck is a horizontal surface enclosing the top of the cooling tower above the plenum that serves as a working platform for inspection and maintenance.
• Fan stack -The fan stack is a cylinder enclosing the fan, usually with an eased inlet and an expanding discharge for increased fan efficiency.
• Fill -The fill is PVC, wood, metal, or an alternative material that provides extended water surface exposure for evaporative heat transfer.
• Intake louvers -The intake louvers are an arrangement of horizontal blades at the air inlets that prevent escape of falling water while allowing the entry of air.
• Makeup valve -The makeup valve is a valve that introduces fresh water into the collection basin to maintain the desired collecting basin water level.
• Overflow -The overflow is a drain that prevents the collecting basin from overflowing.
• Partition -The partition is a baffle within a multicell cooling tower that is used to prevent air and/or water flow between adjacent cells.
• Plenum -The plenum is the internal cooling tower area between the drift eliminators and the fans.
• Speed reducer -The speed reducer is a right-angle gear box that transmits power to the fan while reducing the driver speed to that required for optimal fan performance.
• Sump -The sump is a depressed portion of the collecting basin from which cold water is drawn to be returned to the connected system. The sump usually contains strainer screens, antivortex devices, and a drain or cleanout connection.
• Distribution system -The distribution system is that portion of a cooling tower that distributes water over the fill area. It usually consists of one or more flanged inlets, flow control valves, internal headers, distribution basins, spray branches, metering orifices, and other related components.

Forced Draft Cooling Towers

Forced draft cooling towers are very similar to induced draft cooling towers. The primary difference is that the air is blown in at the bottom of the tower and exits at the top. Forced draft cooling towers are the forerunner to induced draft cooling towers. Water distribution problems and recirculation difficulties discourage the use of forced draft cooling towers.

<< Cooling Towers | Natural Convection Cooling Towers >>

Purpose

Before the development of cooling towers, rivers, lakes, and cooling ponds were required to supply cooling. Through the development of the mechanical draft cooling tower, as little as one square foot of area is needed for every 1000 square feet required for a cooling pond or lake. Cooling towers minimize the thermal pollution of the natural water heat sinks and allow the reuse of circulating water. An example of the manner in which a cooling tower can fit into a system is shown in Figure 10.

The cooling of the water in a cooling tower is accomplished by the direct contact of water and air. This cooling effect is provided primarily by an exchange of latent heat of vaporization resulting from evaporation of a small amount of water and by a transfer of sensible heat, which raises the temperature of the air. The heat transferred from the water to the air is dissipated to the atmosphere.

<< Boilers | Induced Draft Cooling Towers >>

Introduction

The primary function of a boiler is to produce steam at a given pressure and temperature. To accomplish this, the boiler serves as a furnace where air is mixed with fuel in a controlled combustion process to release large quantities of heat. The pressure-tight construction of a boiler provides a means to absorb the heat from the combustion and transfer this heat to raise water to a temperature such that the steam produced is of sufficient temperature and quality (moisture content) for steam loads.

Boilers

Two distinct heat sources used for boilers are electric probes and burned fuel (oil, coal, etc.) This chapter will use fuel boilers to illustrate the typical design of boilers. Refer to Figure 9 during the following discussion.

The boiler has an enclosed space where the fuel combustion takes place, usually referred to as the furnace or combustion chamber. Air is supplied to combine with the fuel, resulting in combustion. The heat of combustion is absorbed by the water in the risers or circulating tubes. The density difference between hot and cold water is the driving force to circulate the water back to the steam drum. Eventually the water will absorb sufficient heat to produce steam. Steam leaves the steam drum via a baffle, which causes any water droplets being carried by the steam to drop out and drain back to the steam drum. If superheated steam is required, the steam may then travel through a superheater. The hot combustion gasses from the furnace will heat the steam through the superheater’s thin tube walls. The steam then goes to the steam supply system and the various steam loads.

Some boilers have economizers to improve cycle efficiency by preheating inlet feedwater to the boiler. The economizer uses heat from the boiler exhaust gasses to raise the temperature of the inlet feedwater.

Fuel Boiler Components

Figure 9 illustrates a typical fuel boiler. Some of the components are explained below.

• Steam drum -The steam drum separates the steam from the heated water. The water droplets fall to the bottom of the tank to be cycled again, and the steam leaves the drum and enters the steam system. Feedwater enters at the bottom of the drum to start the heating cycle.
• Downcomers -Downcomers are the pipes in which the water from the steam drum travels in order to reach the bottom of the boiler where the water can enter the distribution headers.
• Distribution headers -The distribution headers are large pipe headers that carry the water from the downcomers to the risers.
• Risers -The piping or tubes that form the combustion chamber enclosure are called risers. Water and steam run through these to be heated. The term risers refers to the fact that the water flow direction is from the bottom to the top of the boiler. From the risers, the water and steam enter the steam drum and the cycle starts again.
• Combustion chamber -Located at the bottom of a boiler, the combustion chamber is where the air and fuel mix and burn. It is lined with the risers.

<< Hydraulics | Cooling Towers >>

Hydraulic Operation

The operation of a typical hydraulic system is illustrated in Figure 8. Oil from a tank or reservoir flows through a pipe into a pump. Often a filter is provided on the pump suction to remove impurities from the oil. The pump, usually a gear-type, positive displacement pump, can be driven by an electric motor, air motor, gas or steam turbine, or an internal combustion engine. The pump increases the pressure of the oil. The actual pressure developed depends upon the design of the system.

Most hydraulic systems have some method of preventing overpressure. As seen in Figure 8, one method of pressure control involves returning hydraulic oil to the oil reservoir. The pressure control box shown on Figure 8 is usually a relief valve that provides a means of returning oil to the reservoir upon overpressurization.

The high pressure oil flows through a control valve (directional control). The control valve changes the direction of oil flow, depending upon the desired direction of the load. In Figure 8 the load can be moved to the left or to the right by changing the side of the piston to which the oil pressure is applied. The oil that enters the cylinder applies pressure over the area of the piston, developing a force on the piston rod. The force on the piston rod enables the movement of a load or device. The oil from the other side of the piston returns to a reservoir or tank.

Hazards

The hazards and precautions listed in the previous chapter on air compressors are applicable to hydraulic systems as well, because most of the hazards are associated with high pressure conditions. Any use of a pressurized medium can be dangerous. Hydraulic systems carry all the hazards of pressurized systems and special hazards that are related directly to the composition of the fluid used.

When using oil as a fluid in a high pressure hydraulic system, the possibility of fire or an explosion exists. A severe fire hazard is generated when a break in the high pressure piping occurs and the oil is vaporized into the atmosphere. Extra precautions against fire should be practiced in these areas. If oil is pressurized by compressed air, an explosive hazard exists if the high pressure air comes into contact with the oil, because it may create a diesel effect and subsequent explosion. A carefully followed preventive maintenance plan is the best precaution against explosion.

<< Hazards of Compressed Air | Boilers >>

Hazards of Compressed Air

People often lack respect for the power in compressed air because air is so common and is often viewed as harmless. At sufficient pressures, compressed air can cause serious damage if handled incorrectly. To minimize the hazards of working with compressed air, all safety precautions should be followed closely.

Small leaks or breaks in the compressed air system can cause minute particles to be blown at extremely high speeds. Always wear safety glasses when working in the vicinity of any compressed air system. Safety goggles are recommended if contact lenses are worn. Compressors can make an exceptional amount of noise while running. The noise of the compressor, in addition to the drain valves lifting, creates enough noise to require hearing protection. The area around compressors should normally be posted as a hearing protection zone.

Pressurized air can do the same type of damage as pressurized water. Treat all operations on compressed air systems with the same care taken on liquid systems. Closed valves should be slowly cracked open and both sides should be allowed to equalize prior to opening the valve further. Systems being opened for maintenance should always be depressurized before work begins.

Great care should be taken to keep contaminants from entering air systems. This is especially true for oil. Oil introduced in an air compressor can be compressed to the point where detonation takes place in a similar manner as that which occurs in a diesel engine. This detonation can cause equipment damage and personnel injury.

<< Compressor Coolers | Hydraulics >>

Compressor Coolers

The amount of moisture that air can hold is inversely proportional to the pressure of the air. As the pressure of the air increases, the amount of moisture that air can hold decreases. The amount of moisture that air can hold is also proportional to the temperature of the air. As the temperature of the air increases, the amount of moisture it can hold increases. However, the pressure change of compressed air is larger than the temperature change of the compressed air. This causes the moisture in the air to condense. Moisture in compressed air systems can cause serious damage. The condensed moisture can cause corrosion, water hammers, and freeze damage; therefore, it is important to avoid moisture in compressed air systems. Coolers are used to minimize the problems caused by heat and moisture in compressed air systems.

Coolers used on the discharge of a compressor are called aftercoolers. Their purpose is to remove the heat generated during the compression of the air. The decrease in temperature promotes the condensing of any moisture present in the compressed air. This moisture is collected in condensate traps that are either automatically or manually drained. If the compressor is multi-staged, there may be an intercooler, which is usually located after the first stage discharge and before the second stage suction. The principle of the intercooler is the same as that of the aftercoolers. The result is drier, cooler, compressed air. The structure of a particular cooler depends on the pressure and volume of the air it cools. Figure 7 illustrates a typical compressor air cooler. Air coolers are used because drier compressed air helps prevent corrosion and cooler compressed air allows more air to be compressed for a set volume.

<< Centrifugal Compressors | Hazards of Compressed Air >>

Centrifugal Compressors

The centrifugal compressor, originally built to handle only large volumes of low pressure gas and air (maximum of 40 psig), has been developed to enable it to move large volumes of gas with discharge pressures up to 3,500 psig. However, centrifugal compressors are now most frequently used for medium volume and medium pressure air delivery. One advantage of a centrifugal pump is the smooth discharge of the compressed air. The centrifugal force utilized by the centrifugal compressor is the same force utilized by the centrifugal pump. The air particles enter the eye of the impeller, designated D in Figure 6. As the impeller rotates, air is thrown against the casing of the compressor. The air becomes compressed as more and more air is thrown out to the casing by the impeller blades. The air is pushed along the path designated A, B, and C in Figure 6. The pressure of the air is increased as it is pushed along this path. Note in Figure 6 that the impeller blades curve forward, which is opposite to the backward curve used in typical centrifugal liquid pumps. Centrifugal compressors can use a variety of blade orientation including both forward and backward curves as well as other designs.

There may be several stages to a centrifugal air compressor, as in the centrifugal pump, and the result would be the same; a higher pressure would be produced. The air compressor is used to create compressed or high pressure air for a variety of uses. Some of its uses are pneumatic control devices, pneumatic sensors, pneumatic valve operators, pneumatic motors, and starting air for diesel engines.

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